Alteration of Biodiesel Properties and Automotive Diesel Engine Performance due to Temperature Variation of the Transesterification Process
Abstract
This study aimed to examine the effects of transesterification reaction temperature on the biodiesel properties and diesel engine performance. Biodiesel properties evaluated in this work included viscosity, density, and methyl ester content. Meanwhile, the diesel engine performance testing comprised the examination of the engine’s torque and power. The research was conducted in several stages, viz. producing biodiesel from fresh cooking oil with variations in transesterification temperature of 45℃, 55℃, and 65℃; testing the characteristics of biodiesel produced; blending biodiesel with petroleum diesel to result in B30 biodiesel fuel; and testing biodiesel fuel (B30) in diesel-engined vehicles. It was revealed that the higher transesterification temperature led to the lower biodiesel viscosity, the decreasing value of biodiesel density values, and the higher methyl ester content. Furthermore, it was also demonstrated that increase of the transesterification temperature resulted in the higher value of torque and power generated. However, compared to the petroleum diesel fuel (B0), biodiesel fuel (B30) exhibited the lower values of the engine’s torque and power. The highest average values of torque and power of B30 fueled diesel-engine were 108.11 Nm and 43.51 kW, respectively, provided by the biodiesel produced at the transesterification reaction temperature of 65℃.
of 65℃.
Keywords
Full Text:
PDFReferences
Abed, K. A., El Morsi, A. K., Sayed, M. M., El Shaib, A. A., & Gad, M. S. (2018) Effect of waste cooking-oil biodiesel on performance and exhaust emissions of a diesel engine, Egyptian journal of petroleum, 27, 985-989.
Aini, F., and Tjahjani, S. (2013) Hubungan antara waktu penyimpanan dan nilai viskositas biodiesel minyak biji kapuk, UNESA Journal of Chemistry, 2, 35-41.
Akhihiero, E.T., Audu, T.O.K., and Aluyor, E.O. (2013) Effect of Variation of Temperature on the Transesterification of Jatropha Seed Oil Using Homogeneous Catalyst, Advanced Materials Research, 824, 473-476.
Arumugam, A., & Ponnusami, V. (2017) Production of biodiesel by enzymatic transesterification of waste sardine oil and evaluation of its engine performance, Heliyon, 3, e00486.
Aziz, I. (2010) Uji performance mesin diesel menggunakan biodiesel dari minyak goreng bekas, Jurnal Kimia Valensi, 1, 291-297.
Budiman, A., Kusumaningtyas, R.D., Pradana, Y.S., & Lestari, N.A. (2014) Biodiesel: Bahan Baku, Proses, dan Teknologi, Yogyakarta: Gajah Mada University Press dan Anggota IKAPI
Darmanto, S., and Sigit, A. (2006) Analisa biodiesel minyak kelapa sebagai bahan bakar alternatif minyak diesel, Traksi 4, 64-72.
Dias, J.M.M. (2010) Biodiesel production from wastes: process development and quality control. University of Porto.
Fatmawati, D., and Shakti, P.D. (2013) Reaksi Metanolisis Limbah Minyak Ikan Menjadi Metil Ester Sebagai Bahan Bakar Biodiesel Dengan Menggunakan Katalis Naoh, Jurnal Teknologi Kimia dan Industri, 2, 68-75.
Fleming, W.J. (1982) Automotive torque measurement: A summary of seven different methods, Vehicular Technology Conference, 32, 71-78.
Frederic, N.P. (2013) Pembuatan biodiesel dari minyak biji kapok dengan proses esterifikasi transesterifikasi, Jurnal Teknologi Kimia dan Industri, 2, 262-266.
Fukuda, H., Kondo, A., & Noda, H. (2001) Biodiesel fuel production by transesterification of oils, Journal of bioscience and bioengineering, 92, 405-416.
Gad, M.S., El-Araby, R., Abed, K.A., El-Ibiari, N.N., El Morsi, A.K., & El-Diwani, G.I. (2018) Performance and emissions characteristics of CI engine fueled with palm oil/palm oil methyl ester blended with diesel fuel, Egyptian Journal of Petroleum, 27, 215-219.
Gerpen, J.V. (2005) Biodiesel processing and production, Fuel processing technology, 86, 1097-1107.
Ghadge, S.V., & Raheman, H. (2006) Process optimization for biodiesel production from mahua (Madhuca indica) oil using response surface methodology, Bioresource technology, 97, 379-384.
Gulum, M., Bilgin, A., & Cakmak, A.V. (2017) Production of the lowest viscosity waste cooking oil biodiesel by using ethanol and potassium hydroxide, Journal of Clean Energy Technologies, 5, 289-93.
Heywood, J. B. (1988) Internal Combustion Engine Fundamentals, McGraw-Hill, New York.
Ichsan, M.T., Anis, S., & Widjanarko, D. (2018) Pengaruh campuran biodiesel minyak rumput laut gracilaria verrucosa dengan bahan bakar solar terhadap unjuk kerja dan emisi gas buang mesin diesel, Jurnal Teknik Mesin Indonesia, 13, 12-15.
Istiningrum, R.B., Aprianto, T., and Pamungkas, F.L.U. (2017) Effect of reaction temperature on biodiesel production from waste cooking oil using lipase as biocatalyst, AIP Conference Proceedings, 1911, 1-5.
Kartika, I.A., Yani, M., and Hermawan, D. (2011) Transesterifikasi in situ biji jarak pagar: pengaruh jenis pereaksi, kecepatan pengadukan, dan suhu reaksi terhadap rendemen dan kualitas biodiesel, Jurnal Teknologi Industri Pertanian, 21, 24-33.
Kusuma, S.T., Suryasa, R.B., and Indrayani, N.L. (2019) Torsi dan daya mesin diesel 2.5 l berbahan bakar biodiesel campuran minyak kelapa sawit, Prosiding Seminar Nasional Energi dan Teknologi, 157-164.
Kusumaningtyas, R.D., & Bachtiar, A. (2012) Sintesis Biodisel dari Minyak Biji Karet dengan Variasi Suhu dan Konsentrasi KOH untuk Tahapan Transesterifikasi, Jurnal Bahan Alam Terbarukan, 1, 9-18.
Kusumaningtyas, R.D., Ratrianti, N., Purnamasari, I., & Budiman, A. (2017) Kinetics study of Jatropha oil esterification with ethanol in the presence of tin (II) chloride catalyst for biodiesel production, AIP Conference Proceedings, 1788, 030086.
Liu, X., He, H., Wang, Y., and Zhu, S. (2007) Transesterification of soybean oil to biodiesel using SrO as a solid base catalyst, Catalysis Communications, 8, 1107-1111.
Nguyen, H.C., Liang, S.H., Li, S.Y., Su, C.H., Chien, C.C., Chen, Y.J., & Huong, D.T. M. (2018) Direct transesterification of black soldier fly larvae (Hermetia illucens) for biodiesel production, Journal of the Taiwan Institute of Chemical Engineers, 85, 165-169.
Nisar, J., Razaq, R., Farooq, M., Iqbal, M., Khan, R.A., Sayed, M., & ur Rahman, I. (2017) Enhanced biodiesel production from Jatropha oil using calcined waste animal bones as catalyst, Renewable Energy, 101, 111-119.
Rahman, M.D., Wigraha, N.A., and Widayana, G. (2017) Pengaruh Ukuran Katup Terhadap Torsi dan Daya pada Sepeda Motor Honda Supra Fit, Jurnal Pendidikan Teknik Mesin Undiksha, 8, 45-54.
Radhakrishnan, S., Munuswamy, D.B., Devarajan, Y., & Mahalingam, A. (2018) Effect of nanoparticle on emission and performance characteristics of a diesel engine fueled with cashew nut shell biodiesel, Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 40, 2485-2493.
Risnoyatiningsih, S. (2012) Biodiesel from avocado seeds by transesterification process, Jurnal Teknik Kimia, 5, 345-351.
Sahoo, P.K., & Das, L.M. (2009) Combustion analysis of Jatropha, Karanja and Polanga based biodiesel as fuel in a diesel engine, Fuel, 88, 994-999.
Schuchardt, U., Sercheli, R., and Vargas, R.M. (1998) Transesterification of vegetable oils: a review, Journal of the Brazilian Chemical Society, 9, 199-210.
Simanungkalit, R., and Sitorus, T.B. (2013) Performansi Mesin Sepeda Motor Satu Silinder Berbahan Bakar Premium dan Pertamax Plus dengan Modifikasi Rasio Kompresi, e-Dinamis, 5, 29-36.
Siva, R., Munuswamy, D.B., & Devarajan, Y. (2019) Emission and performance study emulsified orange peel oil biodiesel in an aspirated research engine, Petroleum Science, 16, 180-186.
Sugiawan, Y., and Managi, S. (2016) The environmental Kuznets curve in Indonesia: Exploring the potential of renewable energy, Energy Policy, 98, 187-198.
Usman, R. (2016) Analisis Kegagalan Katup Buang pada Mesin Pembangkit Listrik Tenaga Diesel (PLTD), Jurnal String, 1, 97-106.
Vyas, A.P., Verma, J.L., dan Subrahmanyam, N. (2011) Effects of molar ratio, alkali catalyst concentration and temperature on transesterification of jatropha oil with methanol under ultrasonic irradiation, Advances in Chemical Engineering and Science, 1, 45-50.
Wahyuni, S., Ramli, and Mahrizal. (2015) Pengaruh Suhu Proses dan Lama Pengendapan terhadap Kualitas Biodiesel dari Minyak Jelantah, Pillar of Physics, 6, 33-40.
Zeng, D., Yang, L., & Fang, T. (2017) Process optimization, kinetic, and thermodynamic studies on biodiesel production by supercritical methanol transesterification with CH3ONa catalyst, Fuel, 203, 739-748.
Zhang, Y., Dube, M.A., McLean, D.D., and Kates, M. (2003) Biodiesel production from waste cooking oil: 2. Economic assessment and sensitivity analysis, Bioresource technology, 90, 229-240.
DOI: https://doi.org/10.23955/rkl.v15i2.16007
Article Metrics
Abstract view : 0 timesPDF - 0 times
Refbacks
- There are currently no refbacks.
Copyright (c) 2020 Dwi Widjanarko, Ratna Dewi Kusumaningtyas, Ahmad Afwan Fathoni
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
JURNAL REKAYASA KIMIA & LINGKUNGAN
Jurusan Teknik Kimia Universitas Syiah Kuala, Jl. Tgk. Syech Abdur Rauf No.7, Kopelma Darussalam, Banda Aceh, INDONESIA
PRINCIPAL CONTACT
Nasrul Arahman, Prof. Dr. S.T., M.T.
Phone: +62813-6092-7917
E-mail: rkl@che.usk.ac.id, nasrular@usk.ac.id
SUPPORT CONTACT
Mirna Rahmah Lubis
E-mail: mirna@che.usk.ac.id
Wahyu Rinaldi, ST, M.Sc.
E-mail: wahyu.rinaldi@che.usk.ac.id