Karakteristik Inhibisi Korosi Baja Karbon Di Dalam Larutan HCl Menggunakan Ektrak Daun Tembakau

Adhi Setiawan, Agung Nugroho, Novi Eka Mayangsari, Widiyastuti Widiyastuti

Abstract


Pengembangan inhibitor korosi saat ini telah mengarah pada jenis inhibitor baru yang lebih ramah terhadap lingkungan.  Penggunaan ektrak daun tembakau telah diinvestigasi  sebagai inhibitor korosi yang ramah lingkungan serta efektif dalam menghambat korosi pada baja karbon di dalam larutan HCl 0,5 M. Tujuan dari penelitian ini adalah untuk menganalisis pengaruh konsentrasi inhibitor serta temperature larutan terhadap laju korosi pada baja karbon. Proses inhibisi korosi baja karbon telah dinvestigasi dalam penelitian ini. Kinerja dari inhibitor ektrak daun tembakau dianalisis dengan metode polarisasi linear dan weight loss. Konsentrasi inhibitor yang digunakan dalam penelitian ini yaitu sebesar 0 mg/l, 100 mg/l, 300 mg/l, 500 mg/l, dan 700 mg/l. Suhu immersi baja karbon yang digunakan dalam penelitian ini yaitu 30oC, 50oC, dan 70 oC. Hasil penelitian menunjukkan bahwa laju korosi menurun seiring meningkatnya konsentrasi inhibitor dan menurunnya suhu larutan. Laju korosi baja karbon minimum terjadi pada konsentrasi inhibitor sebesar 700 ppm dan suhu 30 oC yakni sebesar 2,04 mmy dengan efisiensi inhibisi 85,4%. Besarnya energi bebas Gibs dari adsorpsi inhibitor dipermukaan baja karbon sebesar -18,2 kj/mol. Analisis SEM pada permukaan logam menunjukkan bahwa tingkat degradasi logam tertinggi terjadi pada baja karbon di dalam larutan tanpa inhibitor. Analisis EDS dan FTIR menunjukkan produk korosi baja karbon berbentuk berupa oksida dan hidroksida logam.


Keywords


ektrak daun tembakau, inhibitor, korosi, baja karbon, weight loss

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DOI: https://doi.org/10.23955/rkl.v13i2.11182

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