PREPARATION OF CHITOSAN-CELLULOSE COMPOSITE BEADS USING CELLULOSE ISOLATED FROM SUGARCANE BAGASSE
Abstract
Chitosan-cellulose composite beads had been prepared using cellulose isolated from sugarcane bagasse. Sugarcane bagasse was hydrolyzed with H2SO4 with various concentrations (30, 40, and 50%). Cellulose obtained was characterized using Fourier Transform Infrared (FTIR), X-Ray Diffraction (XRD) and Scanning Electron Microscope (SEM). FTIR analysis results inform the existence of typical functional groups of cellulose in the sample. XRD patterns show H2SO4 concentration on the hydrolysis process influence the crystallinity of cellulose. Cellulose was used as a filler in the preparation of chitosan-cellulose composite beads. The results show that cellulose decrease the crystallinity of chitosan.
Keywords
References
Rainey, T. J.; Covey, G. Pulp and paper production from sugarcane bagasse, In Sugarcane‐Based Biofuels and Bioproducts, Willey Blackwell, John Willey & Son, New York, 2016; pp 1-25
Sundarraj, A. A.; Ranganathan, T. V. A review on cellulose and its utilization from agro industrial waste, Drug Invent. Today. 2018, 10(1), 89–94.
Wang, J.; Liu, M.; Duan, C.; Sun, J.; Xu, Y. Preparation and characterization of cellulose-based adsorbent and its application in heavy metal ions removal, Carbohydr. Polym., 2019, 206, 837–843.
Cheng, M.; Qin, Z.; Chen, Y.; Hu, S.; Ren, Z.; Zhu, M. Efficient Extraction of Cellulose Nanocrystals through Hydrochloric Acid Hydrolysis Catalyzed by Inorganic Chlorides under Hydrothermal Conditions, ACS Sustain. Chem. Eng., 2017, 5(6), 4656–4664.
Menon, M. P.; Selvakumar, R.; Suresh kumar, P.; Ramakrishna, S. Extraction and modification of cellulose nanofibers derived from biomass for environmental application, RSC Adv., 2017, 7(68) 42750–42773.
Manzoor, N.; Cao L.; Deng, D.; Liu Z.; Jiang, Y.; Liu, Y. Cellulase extraction from cellulolytic bacteria promoting bioelectricity production by degrading cellulose, J. Electroanal. Chem., 2018, 829, 241–248.
Bian, H.; Gao, Y.; Yang, Y.; Fang G.; Dai, H. Improving cellulose nanofibrillation of waste wheat straw using the combined methods of prewashing, p-toluenesulfonic acid hydrolysis, disk grinding, and endoglucanase post-treatment, Bioresour. Technol., 2018, 256, 321–327.
Candido, A.; Godoy, R. G.; Gonçalves, G.G. Study of Sugarcane Bagasse Pretreatment with Sulfuric Acid as a Step of Cellulose Obtaining, Int. J. Biol. Biomol. Agric. Food Biotechnol. Eng., 2012, 6(1), 6–10.
Javaid, M. A.; Khera, R. A.; Zia, K. M.; Saito, K.; Bhatti, I. A.; Asghar, M. Synthesis and characterization of chitosan modified polyurethane bio-nanocomposites with biomedical potential, Int. J. Biol. Macromol. 2018, 115, 375–384.
Rahmi; Lelifajri; Nurfatimah, R. Preparation of polyethylene glycol diglycidyl ether (PEDGE) crosslinked chitosan/activated carbon composite film for Cd2+ removal, Carbohydr. Polym., 2018, 199, 499–505.
Marlina; Iqhrammullah, M.; Darmadi; Mustafa, I.; Rahmi, The application of chitosan modified polyurethane foam adsorbent, RASĀYAN J. Chem., 2019, 12(1), 494-501.
Song, Y. K.; Chew, I. M. L.; Choong, T. S. Y.; Tan, J.; Tan, K. W. Isolation of Nanocrystalline Cellulose from oil palm empty fruit bunch – A response surface methodology study, MATEC Web Conf., 2017, 60(04009), 1-5
Li, Y.Y.; Wang, B.; Ma, M.G.; Wang B. The Influence of Pre-treatment Time and Sulfuric Acid on Cellulose Nanocrystals, BioResources, 2018, 13(2), 1-5
Chen, G.; Wang, X.; Jiang, Y.; Mu, X.; Liu, H. Insights into the Inhibition of Acidic Hydrolysis of Cellulose by Its Solation, ACS Sustain. Chem. Eng., 2018, 6(8), 10999–11007.
Tyufekchiev, M.; Duan, P.; Schmidt-Rohr, K.; Focil, G. S.; Timko M. T.; Emmert, M. H. Cellulase-Inspired Solid Acids for Cellulose Hydrolysis: Structural Explanations for High Catalytic Activity, ACS Catal., 2018, 8(2), 1464–1468.
Mohan, C. C.; Harini, K.; Aafrin, B. V.; Priya, U. L.; Jenita, P. M.; Babuskin, S.; Sudarshan, S.; Renuka, V.; Sukumar, M. Extraction and characterization of polysaccharides from tamarind seeds, rice mill residue, okra waste and sugarcane bagasse for its Bio-thermoplastic properties, Carbohydr. Polym., 2018, 186, 394–401.
Mahmood, N.; Yuan, Z.; Schmidt, J.; Xu, C. Depolymerization of lignins and their applications for the preparation of polyols and rigid polyurethane foams: A review, Renew. Sustain. Energy Rev., 2016, 60, 317–329.
Yang, J.; Kwon, G.J.; Hwang, K.; Kim, D.Y. Cellulose–Chitosan Antibacterial Composite Films Prepared from LiBr Solution, Polymers, 2018, 10(1058), 1-7
Lin, S.; Chen, L.; Huang, L.; Cao, S.; Luo, X.; Liu, K. Novel antimicrobial chitosan–cellulose composite films bioconjugated with silver nanoparticles, Ind. Crops Prod., 2015, 70, 395–403.
Dong F.; Li, S. Wound Dressings Based on Chitosan-Dialdehyde Cellulose Nanocrystals-Silver Nanoparticles: Mechanical Strength, Antibacterial Activity and Cytotoxicity, Polymers, 2018, 10(6), 673,1-6.
DOI: 10.24815/jn.v19i2.12734
Refbacks
- There are currently no refbacks.


Universitas Syiah Kuala (recognizedly abbreviated as